Try loading one of the examples.
From the File menu choose Examples.. Try the Simple Robot Example
A Specific Block
The best way to learn more about what a block does it to hover your mouse pointer over it, for most blocks one will see a small bit of hovertext detailing the usage of the block.
Deploying Code
Click the Download button in the upper right corner.
Then click the Download! button in the pop-up window.
Uncompress the contents of the zip folder to a new folder
One can easily copy blocks by right clicking the block they wish to copy, and choosing duplicate. NOTE: all blocks that are contained within the block will also be copied.